Radicals
A Radical is a charged group of atoms. Radicals often remain grouped together during chemical reactions. Radicals have a valency in the same way that ions have a valency. Some of the common Radicals are listed below.
| -1 | -2 |
| Nitrate NO3 -
bicarbonate HCO3 - Hydroxide OH- |
Carbonate CO3
-- Sulfate SO4 -- (or sulphate) |
When working out the formula of compounds containing radicals just think of the radical as a single unit as if it is an ordinary ion.
Consider Calcium Nitrate ...
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The Nitrate radical is treated as if it is a single ion. The 'bracket' is placed around the radical for clarity. If you were working out the number of atoms in one molecule of Calcium Nitrate you need to remember that the '2' outside the bracket means two radicals of Nitrate which means two of everything inside the bracket.

ie Calcium Nitrate consists of: 1 atom of Calcium, 2 atoms of Nitrogen and 6 atoms of Oxygen.
Other examples ...
| Compound | Formula | Composition of one Molecule of the Substance |
| Magnesium bicarbonate
|
Mg(HCO3)2
|
1 Magnesium atom, 2 Hydrogen atoms, 2 Carbon atoms, 6 Oxygen atoms |
| Aluminium Sulfate | Al2(SO4)3 | 2 atoms of Aluminium, 3 atoms of Sulfur, 12 atoms of Oxygen |
NOTE: You MUST become confident in writing formulae and working out the number of atoms of elements in a molecule from its formula. If you are not, you will never be able to balance chemical equations.
Radicals - QUIZ